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Chemical Substance Safety Management

Read the MSDS and prevent hazards

인쇄용 교육자료이수 확인란 포함

🎯 학습 목표

  • Understand the 16 sections of the MSDS
  • GHS warning labels can be read.

📚 신입 학습 콘텐츠

You will learn the meaning of 9 GHS pictograms (explosion, flammable, oxidizing, corrosive, toxic, etc.).

GHS Makes It Possible to Recognize Hazards Just by Looking at the Pictures

GHS (Globally Harmonized System) is a system that unifies the classification and labeling of chemical substances worldwide. It is dangerous to handle imported chemical substances when the labels differ by country.

Korea has adopted GHS under the Occupational Safety and Health Act and the Chemical Substance Control Act.

9 Pictograms

A black image is placed inside a red diamond border.

PictureMeaningOn-site Example
💥 ExplosionExplosive, self-reactiveOrganic peroxides, hardener
🔥 FlameFlammable, self-ignitableSyrup, acetone, alcohol
🔥⭕ Flame over a circleOxidizingHydrogen peroxide, nitric acid
💨 Gas cylinderHigh-pressure gasOxygen, argon, nitrogen cylinder
🧪 CorrosionMetal and skin corrosionSulfuric acid, sodium hydroxide
☠️ SkullAcute toxicity (fatal)Cyanide, formaldehyde
❗ Exclamation markIrritant, mild toxicityGeneral cleaning agent
🫁 Health hazardCarcinogenicity, reproductive toxicity, respiratory allergyBenzene, crystalline silica
🐟🌳 EnvironmentHarmful to aquatic environmentHeavy metal-containing chemicals

> Skull ☠️ and exclamation mark ❗ both indicate toxicity, but their intensity differs. If a skull is present, it is lethal even in small amounts.

Signal Words — "Danger" vs "Warning"

  • Danger: More severe level
  • Warning: Relatively less severe level

Even if something is flammable, if the flash point is low, it is labeled "Danger," and if high, "Warning" is used.

6 Mandatory Elements on the Warning Label

  1. Name (Product name)
  2. Pictogram (Graphic symbol)
  3. Signal word (Danger / Warning)
  4. Hazard statement (H-code, e.g., H225 Highly flammable liquid and vapor)
  5. Precautionary statement (P-code, e.g., P210 Keep away from heat/sparks)
  6. Supplier information (Manufacturer/importer, contact details)

Labels Are Also Required on Small Containers

When transferring from a drum to a smaller container, you must also attach a warning label to that container. Many accidents occur due to not following this rule.

> Putting syrup in a PET bottle is absolutely prohibited. There have been repeated incidents of death due to mistaken consumption as beverages.

On-site Check List

  • Is a warning label attached to the container of the chemical substances I use?
  • Do I know how many pictograms there are and what each means?
  • Is the signal word "Danger" or "Warning"?
  • Have I attached a label to the small container?
  • Is the MSDS posted or available in the workplace (legal obligation)

🛠 실습 포인트

  • MSDS 3종 읽기 실습
  • GHS Pictogram Matching Quiz

🔑 핵심 용어

🔗 관련 모듈

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